Batch and column studies for the adsorption of chromium(VI) on low-cost Hibiscus Cannabinus kenaf, a green adsorbent


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نویسندگان: مقداد پیرصاحب , انور اسدی

کلمات کلیدی: Hibiscus Cannabinus kenaf; Hexavalent chromium; Batch adsorption; Fixed-bed column; Regeneration efficiency

نشریه: Journal of the Taiwan Institute of Chemical Engineers , , 68 ,

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کد مقاله 9303
عنوان فارسی مقاله
عنوان لاتین مقاله Batch and column studies for the adsorption of chromium(VI) on low-cost Hibiscus Cannabinus kenaf, a green adsorbent
نوع مقاله مقاله اصیل (پژوهشی، Original)
بالاترین نمایه نامه بین‌المللی ISI
سطح مقاله
IF 2.848
عنوان نشریه Journal of the Taiwan Institute of Chemical Engineers
نوع نشریه خارجی ایندکس شده
شماره نشریه
دوره 68
تاریخ انتشار شمسی 1395/08/11
تاریخ انتشار میلادی
آدرس لینک مقاله/ همایش در شبکه اینترنت http://www.sciencedirect.com/science/article/pii/S1876107016303595
DOI http://dx.doi.org/10.1016/j.jtice.2016.09.022
آدرس علمی (Affiliation) نویسنده متقاضی Department of Environmental Health Engineering, Faculty of Public Health, Kermanshah University of Medical Sciences, Kermanshah, Iran

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Adsorption is one of the excellent ways for heavy metal removal from aqueous solution because of advantages like the low cost, availability, profitability, ease of operation and efficiency. In this study, adsorption potential of a low cost adsorbent Hibiscus Cannabinus kenaf was investigated for Cr(VI) removal from water using batch and continuous mode experiments. Optimum removal of Cr(VI) ions was occurred at pH 7. The kinetic results showed that the Cr(VI) removal followed intraparticle diffusion kinetics with a correlation coefficient greater than 0.94. The adsorption isotherms of Cr(VI) could be described very well by both the Langmuir and Freundlich equations (R2=0.997). The maximum Cr(VI) uptake was found to be 582 µg/g in Langmuir model. Column studies have been carried out to compare these with batch capacities. The Yoon–Nelson and Thomas models were found appropriate for description of the breakthrough curve, whereas the Bohart–Adams model was not match very well. The recovery of Cr(VI) and chemical regeneration of the spent kenaf have also been studied. The high Cr(VI) adsorption capacity and regeneration efficiency of kenaf suggests it as a promising alternative for heavy metal removal specially at near circumneutral pH.

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نویسنده نفر چندم مقاله نویسنده مسئول
مقداد پیرصاحبدومخير
انور اسدیهفتمبلي

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Batch and column studies for the adsorption of chromium(VI) on low-cost Hibiscus Cannabinus kenaf, a green adsorbent.pdf1395/08/071619143دانلود